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The effect of force on a chemical reaction has been visited in three different molecular environments. The results reveal a unifying framework that enables predictions of force-induced reactivity.

Chemists tend to think about the ways in which molecules behave — the shapes they are most likely to adopt, the molecular partners with which they are most likely to bind, or the rates and outcomes of their reactions — in terms of energies. But in the light of reports that applied forces can direct new chemical transformations1,2,3,4, or induce unusual stress responses in materials5,6, it is becoming increasingly profitable to consider molecular behavior in terms of forces. Writing in the Journal of the American Chemical Society, Ambulator et al.7 provide a crucial benchmark for force-induced reactivity